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(R,R,R)-SPIRAP
产品别名
(R,R,R)-SPIRAP
(R)-CrabPhos
((1R,3R,3′R)-3,3′-diethyl-3H,3′H-1,1′-spirobi[isobenzofuran]-7,7′-diyl)bis(diphenylphosphane)
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C43H38O2P2 |
| Molecular weight | 648.71 |
| Application【应用】 | (R,R,R)-SPIRAP is a chiral C2-symmetric spiroketal-containing ligand developed in the Nagorny lab for asymmetric catalysis. It can be used in variety of stereoselective transformations, including: Ir-catalyzed hydroarylation, Pd-catalyzed allylic alkylation, Pd-catalyzed Heck couplings, and Rh-catalyzed hydrogenation. |
| Other Notes【其他说明】 | Design, Synthesis, and Application of Chiral C2-Symmetric Spiroketal-Containing Ligands in Transition-Metal Catalysis |
产品性质
| Assay【测定】 | ≥95% |
| form【形式】 | powder or crystals |
| reaction suitability | reagent type: ligand reaction type: Asymmetric synthesis |
| mp | 226-228 ℃ |
| SMILES string | CC[C@@H](O1)C2=C([C@@]1(O[C@@H]3CC)C4=C3C=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)C(P(C7=CC=CC=C7)C8=CC=CC=C8)=CC=C2 |
安全信息
| Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
