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1,1′-双(二-环己基膦基)二茂铁二氯化钯

[1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)
产品编号:4074901
规格:98%
CAS NO:917511-90-1
包装规格:250 MG,1 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
4074901250 MG577
40749011 G2090
产品别名

917511-90-1

1,1′-双(二-环己基膦基)二茂铁二氯化钯

[1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)

PdCl2(dcypf)

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C34H52Cl2FeP2Pd
Molecular weight
755.90
MDL number
MFCD11656081
PubChem Substance ID【PubChem化学物质编号】
329762337
Application【应用】
1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl2) can be used as a catalyst in the synthesis of:
  • α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.
  • Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH2 group and arylboronic acids.
  • α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.

产品性质
Quality Level【质量水平】
100
Assay【测定】
98%
form【形式】
powder
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
mp
294-300 ℃
storage temp.【储存温度】
−20℃
SMILES string
[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(C2CCCCC2)C3CCCCC3.[CH]4[CH][CH][C]([CH]4)P(C5CCCCC5)C6CCCCC6
InChI
1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2
InChI key
HRAMBTUEZQOQRK-UHFFFAOYSA-L
packaging【包装】
1 g in glass bottle
250 mg in glass bottle
安全信息
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
Eyeshields, Gloves, type N95 (US)
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