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N-(tert-Butyl)-N-((ethoxycarbonothioyl)thio)-3,5-bis(trifluoromethyl)benzamide
产品别名
2022988-45-8
N-(tert-Butyl)-N-((ethoxycarbonothioyl)thio)-3,5-bis(trifluoromethyl)benzamide
Alexanian xanthylation reagent
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C16H17F6NO2S2 |
Molecular weight | 433.43 |
Application【应用】 | As reported by the Alexanian. laboratory, this reagent is used for site-selective, intermolecular C-H xanthylation of alkanes, leading to the rapid diversification of otherwise inert C-H bonds. Once installed, the xanthate group provides direct access to diverse product analogues via several aliphatic C-H transformations, including halogenation, deuteration, vinylation, and hydroxylation. Product is best stored in foil-wrapped vials in the freezer when not in use; however, it can be weighed out on the bench without risk of decomposition. This product is offered collaboratively with UNC-Chapel Hill and Erik Alexanian. |
Other Notes【其他说明】 | C–H Xanthylation: A Synthetic Platform for Alkane Functionalization. |
产品性质
Quality Level【质量水平】 | 100 |
form【形式】 | solid |
mp | 40-46 ℃ |
storage temp.【储存温度】 | −20℃ |
安全信息
Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
WGK | WGK 3 |