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双(3,5-二甲苯基)磷

Bis(3,5-dimethylphenyl)phosphine
产品编号:3414805
CAS NO:71360-06-0
包装规格:500 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
3414805500 MG2190
产品别名

71360-06-0

双(3,5-二甲苯基)磷

Bis(3,5-dimethylphenyl)phosphine

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C16H19P
Molecular weight
242.30
MDL number
MFCD01074629
PubChem Substance ID【PubChem化学物质编号】
329761721
Application【应用】
Bis(3,5-dimethylphenyl)phosphine can be used as a reactant to prepare:
  • Iron(II) chiral diimine diphosphine complexes as catalysts for the asymmetric transfer hydrogenation of ketones.
  • The complex of iridium with biphenol phosphite-phosphine bidentate ligand as an asymmetric catalyst for the hydrogenation of N-arylimines.
  • Chiral phosphines with excellent stereoselectivity by 1, 4 addition reaction with α,β-unsaturated aldehydes using a palladium catalyst.
Legal Information【法律信息】
Kanata Chemical Technologies, Inc. 产品
产品性质
Quality Level【质量水平】
100
form【形式】
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
refractive index【折射率】
n20/D 1.599
density
1.017 g/mL at 25 ℃
functional group【官能团】
phosphine
SMILES string
Cc1cc(C)cc(Pc2cc(C)cc(C)c2)c1
InChI
1S/C16H19P/c1-11-5-12(2)8-15(7-11)17-16-9-13(3)6-14(4)10-16/h5-10,17H,1-4H3
InChI key
GPFIUEZTNRNFGD-UHFFFAOYSA-N
packaging【包装】
100, 500 mg in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H302
Hazard Classifications【危险分类】
Acute Tox. 4 Oral
Storage Class Code【储存分类代码】
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)【闪点(F)】
230.0 °F
Flash Point(C)【闪点(C)】
> 110 ℃
Personal Protective Equipment【个人防护装备】
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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