苄氧基丙酮

C₆H₅CH₂OCH₂COCH₃

164.20

MFCD01863536

24872460

NA.22

Benzyloxyacetone (α-Benzyloxyacetone) is an α-substituted acetone. It undergoes direct aldol reaction with 4-nitrobenzaldehyde in the presence of (S)-BINAM-L-prolinamide/benzoic acid to form predominantly the syn-diasteroisomer.

Benzyloxyacetone (1-Benzyloxy-2-propanone) may be used in the synthesis of:

• 7-benzyloxy-6-methyl-5-hepten-1-yne
• (Z)-2-methylhept-2-en-6-yn-1-o1
• (S)-(+)-1,2-propanediol, 1-benzyl ether

It may be used as a starting material in synthesizing (2S,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane and (2R,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane.

90%

3% (benzyloxy)acetic acid
3% benzyl alcohol

n20/D 1.512 (lit.)

259 ℃ (lit.)

1.04 g/mL at 25 ℃ (lit.)

CC(=O)COCc1ccccc1

1S/C10H12O2/c1-9(11)7-12-8-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3

YHMRKVGUSQWDGZ-UHFFFAOYSA-N

5 g in glass bottle

10 - Combustible liquids

WGK 3

230.0 °F - closed cup

110 ℃ - closed cup

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)