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(S)-(-)-2′-氨基-1,1′-联萘-2-醇

(S)-(-)-2′-Amino-1,1′-binaphthalen-2-ol
产品编号:3331773
规格:97%
CAS NO:137848-29-4
包装规格:100 MG,500 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
3331773100 MG828
3331773500 MG3420
产品别名

137848-29-4

(S)-(-)-2′-氨基-1,1′-联萘-2-醇

(S)-(-)-2′-Amino-1,1′-binaphthalen-2-ol

(S)-(-)-2-Amino-2′-hydroxy-1,1′-binaphthalene

(S)-NOBIN

(S)-(-)-2-氨基-2′-羟基-1,1′-联萘

(S)-NOBIN

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C20H15NO
Molecular weight
285.34
MDL number
MFCD01882346
PubChem Substance ID【PubChem化学物质编号】
329763211
NACRES
NA.22
Application【应用】
(S)-(-)-2′-Amino-1,1′-binaphthalen-2-ol or (S)-NOBIN, is a non-symmetrically substituted 1,1′-binaphthalene ligand. It can be used as a catalyst in the asymmetric synthesis of unnatural α-alkyl amino acids by phase-transfer catalysis (PTC). (S)-NOBIN can also be employed as starting material to prepare N-monoalkyl and N,N-dialkyl (S)-NOBIN analogs by reacting with aldehydes via reductive amination reaction. N-monoaryl derivatives are obtained from NOBIN via Hartwig−Buchwald arylation reaction.
产品性质
Quality Level【质量水平】
100
Assay【测定】
≥96.5% (HPLC)
97%
optical purity【光学纯度】
enantiomeric excess: ≥98.0%
InChI
1S/C20H15NO/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12,22H,21H2
InChI key
HIXQCPGXQVQHJP-UHFFFAOYSA-N
packaging【包装】
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.
安全信息
Pictograms【象形图】
GHS05,GHS09
Signal word【警示用语:】
Danger
Hazard Statements
H318 - H410
Precautionary Statements
P273 - P280 - P305 + P351 + P338 - P501
Hazard Classifications【危险分类】
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
dust mask type N95 (US), Eyeshields, Gloves
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