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(S)-(-)-2′-氨基-1,1′-联萘-2-醇
(S)-(-)-2′-Amino-1,1′-binaphthalen-2-ol
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产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
3331773 | 100 MG | 828 | |||
3331773 | 500 MG | 3420 |
产品别名
137848-29-4
(S)-(-)-2′-氨基-1,1′-联萘-2-醇
(S)-(-)-2′-Amino-1,1′-binaphthalen-2-ol
(S)-(-)-2-Amino-2′-hydroxy-1,1′-binaphthalene
(S)-NOBIN
(S)-(-)-2-氨基-2′-羟基-1,1′-联萘
(S)-NOBIN
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C20H15NO |
Molecular weight | 285.34 |
MDL number | MFCD01882346 |
PubChem Substance ID【PubChem化学物质编号】 | 329763211 |
NACRES | NA.22 |
Application【应用】 | (S)-(-)-2′-Amino-1,1′-binaphthalen-2-ol or (S)-NOBIN, is a non-symmetrically substituted 1,1′-binaphthalene ligand. It can be used as a catalyst in the asymmetric synthesis of unnatural α-alkyl amino acids by phase-transfer catalysis (PTC). (S)-NOBIN can also be employed as starting material to prepare N-monoalkyl and N,N-dialkyl (S)-NOBIN analogs by reacting with aldehydes via reductive amination reaction. N-monoaryl derivatives are obtained from NOBIN via Hartwig−Buchwald arylation reaction. |
产品性质
Quality Level【质量水平】 | 100 |
Assay【测定】 | ≥96.5% (HPLC) 97% |
optical purity【光学纯度】 | enantiomeric excess: ≥98.0% |
InChI | 1S/C20H15NO/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12,22H,21H2 |
InChI key | HIXQCPGXQVQHJP-UHFFFAOYSA-N |
packaging【包装】 | 100, 500 mg in glass bottle Bottomless glass bottle. Contents are inside inserted fused cone. |
安全信息
Pictograms【象形图】 | GHS05,GHS09 |
Signal word【警示用语:】 | Danger |
Hazard Statements | H318 - H410 |
Precautionary Statements | P273 - P280 - P305 + P351 + P338 - P501 |
Hazard Classifications【危险分类】 | Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 |
Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
WGK | WGK 3 |
Personal Protective Equipment【个人防护装备】 | dust mask type N95 (US), Eyeshields, Gloves |