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(S)-(-)-1-苯乙醇

(S)-(-)-1-Phenylethanol
产品编号:3331768
规格:≥98.5% (sum of enantiomers, GC)
CAS NO:1445-91-6
包装规格:5G-F
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
33317685G-F1500
产品别名

1445-91-6

(S)-(-)-1-苯乙醇

(S)-(-)-1-Phenylethanol

(S)-(-)-sec-Phenylethyl alcohol

(-)-Methyl phenyl carbinol

(S)-(-)-α-Methylbenzyl alcohol

(-)-甲基苯基甲醇

(S)-(-)-α-甲基苄醇

(S)-(--苯乙醇

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C8H10O
Molecular weight
122.16
Beilstein
2039797
MDL number
MFCD00064264
PubChem Substance ID【PubChem化学物质编号】
329748080
NACRES
NA.22
General description【一般描述】
(S)-(-)-1-Phenylethanol can be prepared from acetophenone via enantioselective bioreduction in the presence of Rhizopus arrhizus as a biocatalyst.
Application【应用】
(S)-(-)-1-Phenylethanol can be used as:
  • A starting material to prepare (1S,3R,4S)-1-methyl-3,4-diphenyl-3,4-dihydro-1H-isochromene-3,4-diol (a cyclic hemiacetal) by reacting with benzil via dilithiation reaction.
  • A chiral solvent in the symmetric synthesis of substituted spiroundecenetriones via amino acid-catalyzed domino Knoevenagel/Diels-Alder reactions.

产品性质
Quality Level【质量水平】
100
Assay【测定】
≥98.5% (sum of enantiomers, GC)
form【形式】
liquid
optical activity【旋光性】
[α]/D −45±2°, c = 5% in methanol
optical purity【光学纯度】
enantiomeric ratio: ≥97:3 (GC)
refractive index【折射率】
n20/D 1.527
bp
88-89 ℃/10 mmHg (lit.)
mp
9-11 ℃ (lit.)
density
1.012 g/mL at 20 ℃ (lit.)
SMILES string
C[C@H](O)c1ccccc1
InChI
1S/C8H10O/c1-7(9)8-5-3-2-4-6-8/h2-7,9H,1H3/t7-/m0/s1
InChI key
WAPNOHKVXSQRPX-ZETCQYMHSA-N
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H302 - H315 - H319
Precautionary Statements
P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code【储存分类代码】
6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)【闪点(F)】
185.0 °F
Flash Point(C)【闪点(C)】
85 ℃
Personal Protective Equipment【个人防护装备】
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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