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6-溴-1,4-苯并二噁烷
6-Bromo-1,4-benzodioxane
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产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
3329241 | 5 G | 508 |
产品别名
52287-51-1
6-溴-1,4-苯并二噁烷
6-Bromo-1,4-benzodioxane
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C8H7BrO2 |
Molecular weight | 215.04 |
EC number【EC 号】 | 257-817-2 |
MDL number | MFCD00040750 |
PubChem Substance ID【PubChem化学物质编号】 | 24878339 |
NACRES | NA.22 |
General description【一般描述】 | 6-Bromo-1,4-benzodioxane is an aryl halide. It can be synthesized from 1,4-benzodioxane, via bromination with bromine in acetic acid. It undergoes alkoxycarbonylation reaction with sodium tert-butoxide in the presence of CO to yield 2,3-dihydro-benzo[1,4]dioxine-6-carboxylic acid t-butyl ester. |
Application【应用】 | 6-Bromo-1,4-benzodioxane may be used as a starting reagent in the synthesis of chiral diphosphines (SYNPHOS and DIFLUORPHOS). |
产品性质
Quality Level【质量水平】 | 100 |
Assay【测定】 | 97% |
refractive index【折射率】 | n |
bp | 259-260 ℃ (lit.) |
density | 1.598 g/mL at 25 ℃ (lit.) |
SMILES string | Brc1ccc2OCCOc2c1 |
InChI | 1S/C8H7BrO2/c9-6-1-2-7-8(5-6)11-4-3-10-7/h1-2,5H,3-4H2 |
InChI key | LFCURAJBHDNUNG-UHFFFAOYSA-N |
packaging【包装】 | 5 g in glass bottle |
安全信息
Storage Class Code【储存分类代码】 | 10 - Combustible liquids |
WGK | WGK 3 |
Flash Point(F)【闪点(F)】 | 230.0 °F - closed cup |
Flash Point(C)【闪点(C)】 | 110 ℃ - closed cup |
Personal Protective Equipment【个人防护装备】 | Eyeshields, Gloves, multi-purpose combination respirator cartridge (US) |