您的位置：首页 > 产品中心 > 1394957-71-1， (R,S)-Bode Kinetic Resolution Catalyst
(R,S)-Bode Kinetic Resolution Catalyst
产品别名
1394957-71-1
(R,S)-Bode Kinetic Resolution Catalyst
(4aR,9aS)-6-Bromo-4-hydroxy-4,4a,9,9a-tetrahydroindeno[2,1-b][1,4]oxazin-3(2H)-one
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C11H10BrNO3 |
| Molecular weight | 284.11 |
| PubChem Substance ID【PubChem化学物质编号】 | 329768882 |
| NACRES | NA.22 |
| Application【应用】 | The following hydroxamic acid catalyst was shown by Bode and coworkers to assist in the kinetic resolution of cyclic amines through acylation of one enantiomer, which can be controlled using either the (R or S)- or (S or R)-Bode Kinetic Resolution Catalyst, both of which are also available through sigma-aldrich. It can also be employed in the preparation of nonracemic piperidines by kinetic resolution using an α-hydroxy-α′, β-unsaturated ketone in the presence of a pyrrolotriazolium salt. |
| Other Notes【其他说明】 | Expanded substrate scope and catalyst optimization for the catalytic kinetic resolution of N-heterocycles |
产品性质
| Quality Level【质量水平】 | 100 |
| storage temp.【储存温度】 | 15-25℃ |
| SMILES string | O=C(CO1)N(O)[C@@]2([H])[C@]1([H])CC3=CC=C(Br)C=C32 |
| InChI | 1S/C11H10BrNO3/c12-7-2-1-6-3-9-11(8(6)4-7)13(15)10(14)5-16-9/h1-2,4,9,11,15H,3,5H2/t9-,11+/m0/s1 |
| InChI key | FQXSUQCCAHKURK-GXSJLCMTSA-N |
| packaging【包装】 | 100 mg in glass bottle |
安全信息
| Pictograms【象形图】 | GHS07 |
| Signal word【警示用语：】 | Warning |
| Hazard Statements | H302 |
| Precautionary Statements | P301 + P312 + P330 |
| Hazard Classifications【危险分类】 | Acute Tox. 4 Oral |
| Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
