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(R,R)-(–)-2,3-双(叔丁基甲基膦基)喹喔啉
(R,R)-(–)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
产品价格查看更多规格...
| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3328686 | 100 MG | 1820 | |||
| 3328686 | 500 MG | 4790 |
产品别名
866081-62-1
(R,R)-(–)-2,3-双(叔丁基甲基膦基)喹喔啉
(R,R)-(–)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
(R) QuinoxP
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C18H28N2P2 |
| Molecular weight | 334.38 |
| MDL number | MFCD10565649 |
| PubChem Substance ID【PubChem化学物质编号】 | 24884852 |
| NACRES | NA.22 |
| General description【一般描述】 | (R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline is an air-stable C2-symmetric P-stereogenic phosphine ligand. |
| Application【应用】 | Air-Stable and Highly Efficient Chiral Ligands 在合成转化反应中显示高水平手性控制的高效配体，转化反应范围从金属催化芳基硼酸 1,4-加成到烷基化的开环到不对称氢化。 |
| Features and Benefits【特点和优势】 | Advantages of the QuinoxP* Ligands:
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| Citation【引用】 | Yahav-Levi A, et al. "Aryl-bromide reductive elimination from an isolated Pt (IV) complex." Chemical Communications 46(19) (2010): 3324-3326. Fang P and Hou XL. "Asymmetric Copper-Catalyzed Propargylic Substitution Reaction of Propargylic Acetates with Enamines." Organic letters 11.20 (2009): 4612-4615. Imamoto T, et al. "Highly enantioselective hydrosilylation of simple ketones catalyzed by rhodium complexes of P-chiral diphosphine ligands bearing tert-butylmethylphosphino groups." Tetrahedron: Asymmetry 17(4) (2006): 560-565. |
| Legal Information【法律信息】 | QuinoxP is a registered trademark of Nippon Chemical Industry Co., Ltd. |
产品性质
| Quality Level【质量水平】 | 100 |
| Assay【测定】 | ≥95% |
| mp | 100-104 ℃ |
| SMILES string | CP(c1nc2ccccc2nc1P(C)C(C)(C)C)C(C)(C)C |
| InChI | 1S/C18H28N2P2/c1-17(2,3)21(7)15-16(22(8)18(4,5)6)20-14-12-10-9-11-13(14)19-15/h9-12H,1-8H3/t21-,22-/m0/s1 |
| InChI key | DRZBLHZZDMCPGX-VXKWHMMOSA-N |
| packaging【包装】 | 100 mg in clear glass bottle 500 mg in amber glass bottle |
安全信息
| Pictograms【象形图】 | GHS06 |
| Signal word【警示用语：】 | Danger |
| Hazard Statements | H301 - H315 - H319 - H335 - H413 |
| Precautionary Statements | P273 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Acute Tox. 3 Oral - Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects |
| WGK | WGK 3 |
| Personal Protective Equipment【个人防护装备】 | dust mask type N95 (US), Eyeshields, Faceshields, Gloves |
