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(R)-α-乙酰氧基苯乙腈

(R)-α-Acetoxyphenylacetonitrile
产品编号:3327465
规格:≥97.0% (sum of enantiomers, GC)
CAS NO:119718-89-7
包装规格:1 ML
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品价格
产品编号包装单位单价(元)国内现货国外库存询价单
33274651 ML1280
产品别名

119718-89-7

(R)-α-乙酰氧基苯乙腈

(R)-α-Acetoxyphenylacetonitrile

(R)-α-Cyanobenzyl acetate

O-Acetyl-D-mandelonitrile

(R)-α-氰基苄醇乙酸酯

O-乙酰基-D-苯乙醇腈

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C10H9NO2
Molecular weight
175.18
Beilstein
4293296
MDL number
MFCD00191699
PubChem Substance ID【PubChem化学物质编号】
329747153
NACRES
NA.22
Application【应用】
(R)-α-Acetoxyphenylacetonitrile can be used as a model compound in the iodine promoted as well as t-BuONO-assisted secondary amides synthesis via an aryl N-addition reaction to the -CN group of nitriles.
产品性质
Assay【测定】
≥97.0% (sum of enantiomers, GC)
optical activity【旋光性】
[α]20/D +8.0±0.5°, c = 10% in chloroform
refractive index【折射率】
n20/D 1.506
density
1.115 g/mL at 20 ℃ (lit.)
SMILES string
CC(=O)O[C@@H](C#N)c1ccccc1
InChI
1S/C10H9NO2/c1-8(12)13-10(7-11)9-5-3-2-4-6-9/h2-6,10H,1H3/t10-/m0/s1
InChI key
MUXDFYRMYMEGCM-JTQLQIEISA-N
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H302 + H312 + H332 - H315 - H319 - H335
Precautionary Statements
P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Hazard Classifications【危险分类】
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)【闪点(F)】
235.4 °F - closed cup
Flash Point(C)【闪点(C)】
113 ℃ - closed cup
Personal Protective Equipment【个人防护装备】
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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