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4-苄酰氧基-四甲基哌啶氧自由基
4-Hydroxy-TEMPO benzoate, free radical
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产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
3314848 | 1 G | 671 |
产品别名
3225-26-1
4-苄酰氧基-四甲基哌啶氧自由基
4-Hydroxy-TEMPO benzoate, free radical
4-Hydroxy-TEMPO benzoate
4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-oxyl benzoate
4-苯甲酰氧基-2,2,6,6-四甲基哌啶-1-氧基自由基
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C16H22NO3 |
Molecular weight | 276.35 |
Beilstein | 1431263 |
MDL number | MFCD00075563 |
PubChem Substance ID【PubChem化学物质编号】 | 24863101 |
NACRES | NA.22 |
General description【一般描述】 | 4-Hydroxy-TEMPO benzoate is a 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivative. |
Application【应用】 | 次氯酸盐/亚溴酸盐-硝基氧氧化体系的循环催化剂,该体系用于醇转化生成醛、酮和羧酸。它避开了催化或化学计量重金属氧化剂的使用。 4-Hydroxy-TEMPO benzoate was employed as spin probe to investigate the mechanism of synthesis of SBA-15 and to evaluate its surface properties and pore structure by electron paramagnetic resonance spectroscopy (EPR). It was also used for the functionalization of various polydienes (polybutadiene and polyisoprene). Functionalized polydienes were analyzed by gel permeation chromatography. |
产品性质
Assay【测定】 | 97% |
mp | 99-101 ℃ (lit.) |
SMILES string | CC1(C)CC(CC(C)(C)N1[O])OC(=O)c2ccccc2 |
InChI | 1S/C16H22NO3/c1-15(2)10-13(11-16(3,4)17(15)19)20-14(18)12-8-6-5-7-9-12/h5-9,13H,10-11H2,1-4H3 |
InChI key | MJEDTBDGYVATPI-UHFFFAOYSA-N |
packaging【包装】 | 1 g in glass bottle |
安全信息
Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
WGK | WGK 3 |
Personal Protective Equipment【个人防护装备】 | Eyeshields, Gloves, type N95 (US) |