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4-苄酰氧基-四甲基哌啶氧自由基

4-Hydroxy-TEMPO benzoate, free radical
产品编号:3314848
规格:97%
CAS NO:3225-26-1
包装规格:1 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
33148481 G671
产品别名

3225-26-1

4-苄酰氧基-四甲基哌啶氧自由基

4-Hydroxy-TEMPO benzoate, free radical

4-Hydroxy-TEMPO benzoate

4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-oxyl benzoate

4-苯甲酰氧基-2,2,6,6-四甲基哌啶-1-氧基自由基

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C16H22NO3
Molecular weight
276.35
Beilstein
1431263
MDL number
MFCD00075563
PubChem Substance ID【PubChem化学物质编号】
24863101
NACRES
NA.22
General description【一般描述】
4-Hydroxy-TEMPO benzoate is a 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivative.
Application【应用】
次氯酸盐/亚溴酸盐-硝基氧氧化体系的循环催化剂,该体系用于醇转化生成醛、酮和羧酸。它避开了催化或化学计量重金属氧化剂的使用。
4-Hydroxy-TEMPO benzoate was employed as spin probe to investigate the mechanism of synthesis of SBA-15 and to evaluate its surface properties and pore structure by electron paramagnetic resonance spectroscopy (EPR). It was also used for the functionalization of various polydienes (polybutadiene and polyisoprene). Functionalized polydienes were analyzed by gel permeation chromatography.
产品性质
Assay【测定】
97%
mp
99-101 ℃ (lit.)
SMILES string
CC1(C)CC(CC(C)(C)N1[O])OC(=O)c2ccccc2
InChI
1S/C16H22NO3/c1-15(2)10-13(11-16(3,4)17(15)19)20-14(18)12-8-6-5-7-9-12/h5-9,13H,10-11H2,1-4H3
InChI key
MJEDTBDGYVATPI-UHFFFAOYSA-N
packaging【包装】
1 g in glass bottle
安全信息
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
Eyeshields, Gloves, type N95 (US)
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