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(4S)-2-[2-(二苯基膦)苯基]-4,5-二氢-5,5-二甲基-4-(1-甲基乙基)-噁唑
(4S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-5,5-dimethyl-4-(1-methylethyl)-oxazole
产品别名
1152313-76-2
(4S)-2-[2-(二苯基膦)苯基]-4,5-二氢-5,5-二甲基-4-(1-甲基乙基)-噁唑
(4S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-5,5-dimethyl-4-(1-methylethyl)-oxazole
(S)-5,5-(Dimethyl)-i-Pr-PHOX
(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-5,5-dimethyl-4,5-dihydrooxazole
(S)-2-(2-(二苯基膦)苯基)-4-异丙基-5,5-二甲基-4,5-二氢噁唑
(S)-5,5-(二甲基)-i-Pr-PHOX
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C26H28NOP |
| Molecular weight | 401.48 |
| MDL number | MFCD16621462 |
| PubChem Substance ID【PubChem化学物质编号】 | 329763666 |
| NACRES | NA.22 |
| Application【应用】 | Use of 5,5-(Dimethyl)-i-Pr-PHOX as a Practical Equivalent to t-Bu-PHOX in Asymmetric Catalysis Design, Synthesis, and Applications of Potential Substitutes of t-Bu-Phosphinooxazoline in Pd-Catalyzed Asymmetric Transformations and Their Use for the Improvement of the Enantioselectivity in the Pd-Catalyzed Allylation Reaction of Fluorinated Allyl Enol Carbonates (S)-5,5-(Dimethyl)-i-Pr-PHOX is a phosphinooxazoline ligand (PHOX), belongs to the class of non-C2 symmetric chiral ligand. It can be used in:
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产品性质
| Assay【测定】 | 97% |
| mp | 124-128 ℃ |
| SMILES string | CC(C)[C@@H]1N=C(OC1(C)C)c2ccccc2P(c3ccccc3)c4ccccc4 |
| InChI | 1S/C26H28NOP/c1-19(2)24-26(3,4)28-25(27-24)22-17-11-12-18-23(22)29(20-13-7-5-8-14-20)21-15-9-6-10-16-21/h5-19,24H,1-4H3/t24-/m0/s1 |
| InChI key | JGUZEKBWCGNHHN-DEOSSOPVSA-N |
| packaging【包装】 | 500 mg in glass bottle |
安全信息
| Pictograms【象形图】 | GHS06 |
| Signal word【警示用语：】 | Danger |
| Hazard Statements | H301 - H315 - H319 - H335 - H413 |
| Precautionary Statements | P273 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Acute Tox. 3 Oral - Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects |
| WGK | WGK 3 |
