您的位置：首页 > 产品中心 > 150639-33-1， (4S)-(+)-苯基-α-[(4S)-苯基噁唑烷-2-亚基]-2-噁唑啉-2-乙腈
(4S)-(+)-苯基-α-[(4S)-苯基噁唑烷-2-亚基]-2-噁唑啉-2-乙腈
(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile
产品别名
150639-33-1
(4S)-(+)-苯基-α-[(4S)-苯基噁唑烷-2-亚基]-2-噁唑啉-2-乙腈
(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile
(S,S)-4-Phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile
(S,S)-4-苯基-α-(4-苯基噁唑烷-2-亚基)-2-噁唑啉-2-乙腈
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C20H17N3O2 |
| Molecular weight | 331.37 |
| MDL number | MFCD00192394 |
| PubChem Substance ID【PubChem化学物质编号】 | 24866118 |
| NACRES | NA.22 |
| General description【一般描述】 | (4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile is a C2-symmetric chiral bisoxazoline (BOX) ligand. |
| Application【应用】 | (4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile/Re(V)-oxo complex can catalyze the asymmetric hydrosilylation of ketones. 对映选择性催化反应的配体。由于噁唑啉氮具有对各种金属的强亲合性，因此可容易地形成双齿配位络合物。 |
产品性质
| Assay【测定】 | 97% |
| optical activity【旋光性】 | [α]20/D +364°, c = 1 in chloroform |
| mp | 146-148 ℃ (lit.) |
| SMILES string | N#C\C(=C1\N[C@H](CO1)c2ccccc2)C3=N[C@H](CO3)c4ccccc4 |
| InChI | 1S/C20H17N3O2/c21-11-16(19-22-17(12-24-19)14-7-3-1-4-8-14)20-23-18(13-25-20)15-9-5-2-6-10-15/h1-10,17-18,22H,12-13H2/b19-16-/t17-,18-/m1/s1 |
| InChI key | QVVGSAYHUSBCQV-SRKGJJLTSA-N |
| packaging【包装】 | 1 g in glass bottle |
安全信息
| Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
| WGK | WGK 3 |
| Personal Protective Equipment【个人防护装备】 | dust mask type N95 (US), Eyeshields, Gloves |
