2-烯丙基环己酮

H₂C=CHCH₂C₆H₉(=O)

138.21

202-352-2

MFCD00043548

24865329

NA.22

2-Allylcyclohexanone is a β,γ-unsaturated ketone. Selective oxidation of 2-allylcyclohexanone by benzonitrile-hydrogen peroxide has been reported. Asymmetric synthesis of 2-alkylcyclohexanones by alkylation of cyclohexanone enamines (III) of L-proline ester derivatives has been described. Oxidation of 2-allylcyclohexanone by 90% hydrogen peroxide catalyzed by arsonated polystyrene has been studied.

2-Allylcyclohexanone may be used in the synthesis of the following:

• bicyclo[3.3.1]non-2-en-9-one
• R-(-)-epilachnene, an antipode of the defensive droplets from the Mexican bean beetle, Epilachna varivestis

100

97%

n20/D 1.469 (lit.)

94 ℃/23 mmHg (lit.)

0.927 g/mL at 25 ℃ (lit.)

C=CCC1CCCCC1=O

1S/C9H14O/c1-2-5-8-6-3-4-7-9(8)10/h2,8H,1,3-7H2

UPGHEUSRLZSXAE-UHFFFAOYSA-N

1, 5 g in glass bottle

GHS07

Warning

H302 + H312 + H332 - H315 - H319 - H335

P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Respiratory system

10 - Combustible liquids

WGK 3

235.4 °F - closed cup

113 ℃ - closed cup

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter