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[2-(二丁基膦基甲基)-6-(二乙基氨基甲基)吡啶]羰基氯氢化钌(II)

[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
产品编号:3268969
CAS NO:863971-62-4
包装规格:100 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
3268969100 MG1110
产品别名

863971-62-4

[2-(二丁基膦基甲基)-6-(二乙基氨基甲基)吡啶]羰基氯氢化钌(II)

[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)

[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride

Milstein Catalyst Precursor

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C20H36ClN2OPRu
Molecular weight
488.01
MDL number
MFCD16038117
PubChem Substance ID【PubChem化学物质编号】
329765059
NACRES
NA.22
General description【一般描述】
May contain up to 10% acetone and/or THF.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Application【应用】
Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2
Precursor to active Ru catalyst for the dehydrogenative coupling of amines and alcohols to form amide bonds.
产品性质
reaction suitability
core: ruthenium
reagent type: catalyst
greener alternative product characteristics【环保替代产品特性】
Catalysis
Learn more about the Principles of Green Chemistry.
greener alternative category【环保替代产品分类】
Aligned
SMILES string
Cl[RuH].[C-]#[O+].CCN(CC)Cc1cccc(CP(C(C)(C)C)C(C)(C)C)n1
InChI
1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;/q;;;+1;/p-1
InChI key
RZCAJPSOQUIHSH-UHFFFAOYSA-M
packaging【包装】
100, 500 mg in glass bottle
安全信息
Pictograms【象形图】
GHS07,GHS08
Signal word【警示用语:】
Warning
Hazard Statements
H319 - H351
Precautionary Statements
P281 - P305 + P351 + P338
Hazard Classifications【危险分类】
Carc. 2 - Eye Irrit. 2
Supp Hazards【补充剂危害】
EUH019
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
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