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[2-(二叔丁基膦基甲基)-6-(二乙基氨基甲基)吡啶]羰基氯氢化钌(II)
[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
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产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
3268969 | 100 MG | 1110 |
产品别名
863971-62-4
[2-(二叔丁基膦基甲基)-6-(二乙基氨基甲基)吡啶]羰基氯氢化钌(II)
[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)
[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride
Milstein Catalyst Precursor
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C20H36ClN2OPRu |
Molecular weight | 488.01 |
MDL number | MFCD16038117 |
PubChem Substance ID【PubChem化学物质编号】 | 329765059 |
NACRES | NA.22 |
General description【一般描述】 | May contain up to 10% acetone and/or THF. We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. |
Application【应用】 | Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols. Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2 Precursor to active Ru catalyst for the dehydrogenative coupling of amines and alcohols to form amide bonds. |
产品性质
reaction suitability | core: ruthenium reagent type: catalyst |
greener alternative product characteristics【环保替代产品特性】 | Catalysis Learn more about the Principles of Green Chemistry. |
greener alternative category【环保替代产品分类】 | Aligned |
SMILES string | Cl[RuH].[C-]#[O+].CCN(CC)Cc1cccc(CP(C(C)(C)C)C(C)(C)C)n1 |
InChI | 1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;/q;;;+1;/p-1 |
InChI key | RZCAJPSOQUIHSH-UHFFFAOYSA-M |
packaging【包装】 | 100, 500 mg in glass bottle |
安全信息
Pictograms【象形图】 | GHS07,GHS08 |
Signal word【警示用语:】 | Warning |
Hazard Statements | H319 - H351 |
Precautionary Statements | P281 - P305 + P351 + P338 |
Hazard Classifications【危险分类】 | Carc. 2 - Eye Irrit. 2 |
Supp Hazards【补充剂危害】 | EUH019 |
Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
WGK | WGK 3 |