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N-环己基马来酰亚胺
N-Cyclohexylmaleimide
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产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
3169947 | 5 G | 1650 |
产品别名
1631-25-0
N-环己基马来酰亚胺
N-Cyclohexylmaleimide
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C10H13NO2 |
Molecular weight | 179.22 |
EC number【EC 号】 | 216-630-6 |
MDL number | MFCD00043904 |
PubChem Substance ID【PubChem化学物质编号】 | 24863825 |
NACRES | NA.22 |
General description【一般描述】 | N-Cyclohexylmaleimide (CHMI, NCMI) is a cyclic imide. Diels-Alder reactions of 9-hydroxymethylanthracene with CHMI catalyzed by hydrophobic nanospace confined within the self-assembled Pd6 open cage bearing triimidazole walls have been reported. It undergoes Diels-Alder reactions with various aromatic hydrocarbons promoted by self-assembled coordination cage. This cage acts as nanometer-sized molecular flask and hence promotes this reaction. CHMI is reported to undergo radical polymerization readily under various polymerization conditions to afford poly(CHMI), having excellent thermal stability. |
Application【应用】 | N-Cyclohexylmaleimide (CHMI, NCMI) may be used for the preparation of hyperbranched copolymers of p-(chloromethyl)styrene (CMS) and NCMI, via atom transfer radical copolymerization reaction. N-Cyclohexylmaleimide contaminated with N-cyclohexylmaleamic acid (less than 0.9 wt%) may be used for the heat-resistant poly(methyl methacrylate) resin free from coloration and for methyl methacrylate homopolymer. It may be used as monomer in the preparation of styrene/N-cyclohexylmaleimide copolymers with small polydispersities and controlled molecular weights, via free radical copolymerization. It may be used in the synthesis of hyperbranched copolymers by the atom transfer radical copolymerization with p-(chloromethyl)styrene catalyzed by CuCl/2,2′-bipyridine in cyclohexanone or anisole. |
产品性质
Quality Level【质量水平】 | 100 |
Assay【测定】 | 97% |
mp | 89-91 ℃ (lit.) |
SMILES string | O=C1C=CC(=O)N1C2CCCCC2 |
InChI | 1S/C10H13NO2/c12-9-6-7-10(13)11(9)8-4-2-1-3-5-8/h6-8H,1-5H2 |
InChI key | BQTPKSBXMONSJI-UHFFFAOYSA-N |
packaging【包装】 | 5 g in glass bottle |
安全信息
Pictograms【象形图】 | GHS06,GHS09 |
Signal word【警示用语:】 | Danger |
Hazard Statements | H301 - H315 - H317 - H319 - H335 - H410 |
Precautionary Statements | P261 - P273 - P280 - P301 + P310 - P302 + P352 - P305 + P351 + P338 |
Hazard Classifications【危险分类】 | Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1A - STOT SE 3 |
Target Organs【靶器官】 | Respiratory system |
Storage Class Code【储存分类代码】 | 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
WGK | WGK 3 |
Personal Protective Equipment【个人防护装备】 | dust mask type N95 (US), Eyeshields, Gloves |