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2,6-双[(3aS,8aR)-3a,8a-二氢-8H-茚并[1,2-d]噁唑啉-2-基]吡啶

2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine
产品编号:3163989
CAS NO:185346-09-2
包装规格:250 MG,1 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
3163989250 MG1230
31639891 G3950
产品别名

185346-09-2

2,6-双[(3aS,8aR)-3a,8a-二氢-8H-茚并[1,2-d]噁唑啉-2-基]吡啶

2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine

(3aS,3′aS,8aR,8′aR)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole

(3aS,8aR)-in-pybox

Dimethlyammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2′-bis(dip-tolylphosphino)1,1′-binaphthyl]diruthenate(ΙΙ)

(3aS,3′aS,8aR,8′aR)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C25H19N3O2
Molecular weight
393.44
MDL number
MFCD05861599
PubChem Substance ID【PubChem化学物质编号】
329760573
NACRES
NA.22
Application【应用】
Reactant involved in synthesis of:
  • Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
  • Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
  • Chiral N,N,N-tridentate pybos and pyboxazine ligands
产品性质
Quality Level【质量水平】
100
optical activity【旋光性】
[α]20/D -375°, c = 1 in dichloromethane (typical)
mp
276-281 ℃
SMILES string
C1[C@H]2OC(=N[C@H]2c3ccccc13)c4cccc(n4)C5=N[C@@H]6[C@@H](Cc7ccccc67)O5
InChI
1S/C25H19N3O2/c1-3-8-16-14(6-1)12-20-22(16)27-24(29-20)18-10-5-11-19(26-18)25-28-23-17-9-4-2-7-15(17)13-21(23)30-25/h1-11,20-23H,12-13H2/t20-,21-,22+,23+/m1/s1
InChI key
BZSJUFJXCHHRHW-LUKWVAJMSA-N
packaging【包装】
250 mg in glass insert
1 g in glass bottle
安全信息
Hazard Statements
H413
Hazard Classifications【危险分类】
Aquatic Chronic 4
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
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