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1-哌啶甲腈

1-Piperidinecarbonitrile
产品编号:3114658
规格:99%
CAS NO:1530-87-6
包装规格:5 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
31146585 G2090
产品别名

1530-87-6

1-哌啶甲腈

1-Piperidinecarbonitrile

NSC 26965

Pentamethylenecyanamide

1-Cyanopiperidine

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C6H10N2
Molecular weight
110.16
EC number【EC 号】
216-233-8
MDL number
MFCD00006477
PubChem Substance ID【PubChem化学物质编号】
24852808
NACRES
NA.22
General description【一般描述】
1-Piperidinecarbonitrile in tetrahydrofuran (THF) reacts with a solution of piperidyl lithium in THF at 0℃ to yield lithium[1,1,3,3-bis(pentamethylene)guanidinate]. It participates in thermal decomposition of the 2H-azaphosphirene metal complexes to yield the Δ3-1,3,2-oxazaphospholene complexes and the Δ3-1,3,2-thiazaphospholene complexes.
Application【应用】
1-Piperidinecarbonitrile was used in the preparation of 1-selenocarbamoylpiperidine.
Reactant for:
Cycloaddition reactions
Ring-expansion reactions of tungsten complexes
N-CN bond cleavage
Retro-Diels-Alder reactions
Regioselective electrochemical α-methoxylation
Synthesis of de-O-chloroacetylation reagents
产品性质
Quality Level【质量水平】
100
Assay【测定】
99%
form【形式】
liquid
refractive index【折射率】
n20/D 1.47 (lit.)
bp
102 ℃/10 mmHg (lit.)
density
0.951 g/mL at 25 ℃ (lit.)
SMILES string
N#CN1CCCCC1
InChI
1S/C6H10N2/c7-6-8-4-2-1-3-5-8/h1-5H2
InChI key
NVPICXQHSYQKGM-UHFFFAOYSA-N
packaging【包装】
5 g in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H302 + H312 + H332 - H315 - H319 - H335
Precautionary Statements
P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Hazard Classifications【危险分类】
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)【闪点(F)】
206.6 °F - closed cup
Flash Point(C)【闪点(C)】
97 ℃ - closed cup
Personal Protective Equipment【个人防护装备】
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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