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Garg 4,5-indolyne precursor
产品别名
1259448-37-7
Garg 4,5-indolyne precursor
4-(Trimethylsilyl)-1H-indol-5-yl trifluoromethanesulfonate
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C12H14F3NO3SSi |
| Molecular weight | 337.39 |
| MDL number | MFCD25976536 |
| PubChem Substance ID【PubChem化学物质编号】 | 329768491 |
| NACRES | NA.22 |
| General description【一般描述】 | Garg 4,5-indolyne precursor is an indolyne precursor developed by Professor Neil Garg and coworkers. It is widely used for the synthesis of various N-heterocyclic based compounds. It is also useful for the preparation of substituted indoles (Diels–Alder and azide cycloaddition products). |
| Application【应用】 | Indolyne precursor can be activated under mild fluoride conditions, which are highly reactive with dienes and other dipolariphiles (e.g. azides) to provide cycloaddition products containing an indole motif. |
| Other Notes【其他说明】 | Indolyne Experimental and Computational Studies: Synthetic Applications and Origins of Selectivities of Nucleophilic Additions Regioselective reactions of 3; 4-pyridynes enabled by the aryne distortion model |
产品性质
| Quality Level【质量水平】 | 100 |
| Assay【测定】 | 95% |
| mp | 43-48 ℃ |
| storage temp.【储存温度】 | 2-8℃ |
| SMILES string | O=S(OC1=C([Si](C)(C)C)C2=C(NC=C2)C=C1)(C(F)(F)F)=O |
| InChI | 1S/C12H14F3NO3SSi/c1-21(2,3)11-8-6-7-16-9(8)4-5-10(11)19-20(17,18)12(13,14)15/h4-7,16H,1-3H3 |
| InChI key | LLCJFYYASDIOJN-UHFFFAOYSA-N |
| packaging【包装】 | 1 g in glass bottle |
安全信息
| Pictograms【象形图】 | GHS07 |
| Signal word【警示用语：】 | Warning |
| Hazard Statements | H315 - H319 - H335 |
| Precautionary Statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
| WGK | WGK 3 |
