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Difluoromethyl Phenyl Sulfone

产品编号:3077091
规格:≥97%
CAS NO:1535-65-5
包装规格:1 G,10 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
30770911 G612
307709110 G4220
产品别名

1535-65-5

Difluoromethyl Phenyl Sulfone

[(Difluoromethyl)sulfonyl]benzene

PhSO2CF2H

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C7H6F2O2S
Molecular weight
192.18
Beilstein
2259218
MDL number
MFCD01050170
PubChem Substance ID【PubChem化学物质编号】
329765583
NACRES
NA.22
Application【应用】
Reagent Used for
  • Reductive silylation and the preparation of trifluoro- and difluoromethylsilanes by reductive coupling of fluoromethyl sulfones, sulfoxides and sulfides with chlorosilanes
  • Fluoroalkylation/chloroalkylation of α,β-enones, arynes, acetylenic ketones and other Michael acceptors
  • Difluoromethylation of primary alkyl halides via nucleophilic substitution-reductive desulfonylation

Reagent used in Preparation of
  • α-difluoromethyl amines via stereoselective (phenylsulfonyl)difluoromethylation of chiral sulfinyl aldimines
  • Anti-difluoropropanediols via potassium tert-butoxide-catalyzed difluoromethylenation of aldehydes
  • β-difluoromethylated and β-difluoromethylenated alcohols and amines by regioselective nucleophilic difluoromethylation of 1,2-cyclic sulfates and sulfamidates
  • Difluoroalkenes from alkyl halides via nucleophilic substitution-elimination
  • Difluoromethyl alcohol derivatives from enolizable and non-enolizable carbonyl compounds using nucleophilic phenylsulfonyldifluoromethylation-reductive desulfonylation strategy
  • Fluoromethylated vicinal ethylenediamines via fluoromethylation of chiral α-aminobutanesulfinimines with (phenylsulfonyl)fluoromethanes followed by reductive desulfonylation and alcoholysis
产品性质
Quality Level【质量水平】
100
Assay【测定】
≥97%
SMILES string
FC(F)S(=O)(=O)c1ccccc1
InChI
1S/C7H6F2O2S/c8-7(9)12(10,11)6-4-2-1-3-5-6/h1-5,7H
InChI key
LRHDNAVPELLXDL-UHFFFAOYSA-N
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319
Precautionary Statements
P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code【储存分类代码】
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)【闪点(F)】
264.0 °F
Flash Point(C)【闪点(C)】
128.9 ℃
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