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二氯三苯基膦[双(2-(乙硫基)乙基)胺]钌(II)
Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)
产品别名
1462397-86-9
二氯三苯基膦[双(2-(乙硫基)乙基)胺]钌(II)
Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)
Ru-SNS catalyst
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C26H34Cl2NPRuS2 |
| Molecular weight | 627.63 |
| MDL number | MFCD26960799 |
| PubChem Substance ID【PubChem化学物质编号】 | 329765759 |
| NACRES | NA.22 |
| General description【一般描述】 | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. |
| Application【应用】 | Catalyst for the hydrogenation of esters to alcohols. Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents. Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters |
| Other Notes【其他说明】 | "The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)." |
| Legal Information【法律信息】 | This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product. |
产品性质
| Quality Level【质量水平】 | 100 |
| Assay【测定】 | 97% |
| reaction suitability | core: ruthenium reagent type: catalyst |
| greener alternative product characteristics【环保替代产品特性】 | Catalysis Learn more about the Principles of Green Chemistry. |
| mp | 300-310 ℃ |
| greener alternative category【环保替代产品分类】 | Aligned |
| SMILES string | CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3 |
| InChI | 1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2 |
| InChI key | ZQGMNGJIEYHKBR-UHFFFAOYSA-L |
| packaging【包装】 | 100, 500 mg in glass bottle |
安全信息
| Pictograms【象形图】 | GHS06 |
| Signal word【警示用语：】 | Danger |
| Hazard Statements | H302 + H312 - H331 |
| Precautionary Statements | P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P311 |
| Hazard Classifications【危险分类】 | Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral |
| Storage Class Code【储存分类代码】 | 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
| WGK | WGK 3 |
