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Dichlorotriphenylphosphine[2-(diphenylphosphino)-N-(2-pyridinylmethyl)ethanamine]ruthenium(II)
产品别名
1388712-91-1
Dichlorotriphenylphosphine[2-(diphenylphosphino)-N-(2-pyridinylmethyl)ethanamine]ruthenium(II)
Ru-PNN catalyst
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C38H36Cl2N2P2Ru |
MDL number | MFCD26960800 |
PubChem Substance ID【PubChem化学物质编号】 | 329765760 |
NACRES | NA.22 |
General description【一般描述】 | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. |
Application【应用】 | Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents. From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts |
Legal Information【法律信息】 | This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product. |
产品性质
Quality Level【质量水平】 | 100 |
Assay【测定】 | 97% |
reaction suitability | core: ruthenium reagent type: catalyst |
greener alternative product characteristics【环保替代产品特性】 | Catalysis Learn more about the Principles of Green Chemistry. |
mp | 275-295 ℃ |
greener alternative category【环保替代产品分类】 | Aligned |
SMILES string | Cl[Ru]Cl.[H]N(CCP(C1=CC=CC=C1)C2=CC=CC=C2)CC3=NC=CC=C3.P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6 |
InChI | 1S/C20H21N2P.C18H15P.2ClH.Ru/c1-3-10-19(11-4-1)23(20-12-5-2-6-13-20)16-15-21-17-18-9-7-8-14-22-18;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h1-14,21H,15-17H2;1-15H;2*1H;/q;;;;+2/p-2 |
InChI key | JFYJJNHKCBDTMZ-UHFFFAOYSA-L |
packaging【包装】 | 100, 500 mg in glass bottle |
安全信息
Pictograms【象形图】 | GHS06 |
Signal word【警示用语:】 | Danger |
Hazard Statements | H302 + H312 - H331 |
Precautionary Statements | P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P311 |
Hazard Classifications【危险分类】 | Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral |
Storage Class Code【储存分类代码】 | 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
WGK | WGK 3 |