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[rac-乙烯双(4,5,6,7-四氢-1-茚基)]二氯化锆(IV)

Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV)
产品编号:3075955
规格:97%
CAS NO:100163-29-9
包装规格:500 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
3075955500 MG3040
产品别名

100163-29-9

[rac-乙烯双(4,5,6,7-四氢-1-茚基)]二氯化锆(IV)

Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV)

Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C20H24Cl2Zr
Molecular weight
426.53
MDL number
MFCD00672123
PubChem Substance ID【PubChem化学物质编号】
24877859
NACRES
NA.22
Application【应用】
Catalyst for:
  • Regiochemistry in Negishi carboaluminations
  • Polymerization of olefins
  • Diastereoselective intramolecular olefin alkylations
  • Asymmetric carbomagnesiation
  • Reduction of esters to alcohols
  • Enantioselective synthesis of allylic amines
产品性质
Quality Level【质量水平】
100
Assay【测定】
97%
reaction suitability
core: zirconium
reagent type: catalyst
mp
267-271 ℃ (lit.)
SMILES string
Cl[Zr]Cl.[CH]1[CH][C](CC[C]2[CH][CH][C]3CCCC[C]23)[C]4CCCC[C]14
InChI
1S/C20H24.2ClH.Zr/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;;;/h9-12H,1-8,13-14H2;2*1H;/q;;;+2/p-2
InChI key
AKXWJOYQORUUHS-UHFFFAOYSA-L
packaging【包装】
500 mg in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319 - H335
Precautionary Statements
P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
dust mask type N95 (US), Eyeshields, Gloves
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