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三(二亚苄基丙酮)二钯(0)
Tris(dibenzylideneacetone)dipalladium(0)
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| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3062459 | 1g | 1460 | |||
| 3062459 | 5g | 4470 | |||
| 3062459 | 25g | 13370 |
产品别名
51364-51-3
三(二亚苄基丙酮)二钯(0)
Tris(dibenzylideneacetone)dipalladium(0)
Bis[tris(dibenzylideneacetone)palladium(0)]
Pd{2}(dba){3}
基本信息
| 应用 | Tris(dibenzylideneacetone)dipalladium(0) is the most widely used Pd0 precursor complex in synthesis and catalysis, in particular as a catalyst for various coupling reactions. It is used as a catalyst precursor for palladium-catalyzed carbon-nitrogen bond formation, conversion of aryl chlorides, triflates and nonaflates to nitroaromatics. It is used as catalyst for the synthesis of epoxides, alpha-arylation of ketones, in combination with BINAP for the asymmetric heck arylation of olefins, site-selective benzylic sp3 palladium-catalyzed direct arylation and homoallylic diamination of terminal olefins. It also used for palladium-catalyzed one-pot synthesis of tricyclic indolines, in the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles and cross-coupling of aryl halides with aryl boronic acids. |
| 备注 | Handle under nitrogen atmosphere and protect from moisture and air. |
| MDL | MFCD00013310 |
| 分子式 | C51H42O3Pd2 |
| 分子量 | 915.74 |
| 熔点 | 152-155° |
| 灵敏度 | Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures. |
| 形态 | Powder |
| 溶解性 | Soluble in chlorinated solvents, benzene and THF. |
安全信息
| TSCA | 否 |
