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二氯磷酸苯酯

Phenyl Phosphorodichloridate
产品编号:3057454
规格:97%
CAS NO:770-12-7
包装规格:25g,100g,500g
产品类别:进口试剂
品牌:Alfa Aesar
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
305745425g399
3057454100g1018
3057454500g3870
产品别名

770-12-7

二氯磷酸苯酯

Phenyl Phosphorodichloridate

Phenyl Dichlorophosphate

基本信息
应用
Reagent for preparation of phosphate diesters.Phenyl phosphorodichloridate is used in the preparation of symmetrical phosphate diesters. It is used as a phosphorylating agent for alcohols and amines. It is also involved in the preparation of phenylphosphoro di-(1-imidazolidate) and 2-phenyl-bis-triazoloylphosphate, which is used in peptide synthesis. It plays a vital role in the Pfitzner-Moffatt oxidation which involves oxidation of alcohols to the corresponding aldehydes and ketones. Furthermore, it is utilized in Beckmann rearrangement for the preparation of N-phenylacetamide from acetophenone oxime.
备注
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases, alcohols and strong oxidizing agents.
MDL
MFCD00002067
EINECS
212-220-6
分子式
C6H5Cl2O2P
分子量
210.98
熔点
-1°
沸点
241-243°
闪点
112°(233°F)
密度
1.415
折射率
1.5230
灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
形态
Liquid
溶解性
Immiscible with water.
Beilstein
511863
包装组
II
危险类别
22-34
Harmful if swallowed.Causes burns.
安全信息
危险等级
8
安全等级
20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste
RTECS
TD4393000
欧盟危险品标志
  
TSCA
GHS危害和防范说明
GHS符号
  
Hazard Statements
H302-H314-H318
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.
Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
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