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N-甲氧基甲基-N-(三甲基硅烷)苄基胺
N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine
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| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3052663 | 1g | 685 | |||
| 3052663 | 5g | 2200 |
产品别名
93102-05-7
N-甲氧基甲基-N-(三甲基硅烷)苄基胺
N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine
基本信息
| 应用 | N-Methoxymethyl-N-(trimethylsilylmethyl)benzylamine forms azomethine ylides which readily undergo [3+2] cycloaddition to α,??-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields. It reacts with asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines. It is used in the the synthesis of 3-carboxy-1-azabicyclo[2.2.1]heptane derivatives, an important class of physiologically active compounds. |
| 备注 | Moisture & Light Sensitive. Store away from oxidizing agents. |
| MDL | MFCD00674005 |
| EINECS | 000-000-0 |
| 分子式 | C13H23NOSi |
| 分子量 | 237.42 |
| 沸点 | 76°/0.3mm |
| 闪点 | 66°(150°F) |
| 密度 | 0.928 |
| 折射率 | 1.4920 |
| 灵敏度 | Keep Cold. Moisture Sensitive. Light Sensitive. Store under Nitrogen. |
| 形态 | Liquid |
| 溶解性 | Soluble in chloroform, ethyl acetate. |
| Beilstein | 4311216 |
| 危险类别 | 36/37/38 Irritating to eyes, respiratory system and skin. |
安全信息
| 安全等级 | 26-37 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| TSCA | 否 |
GHS危害和防范说明
| GHS符号 |  |
| Hazard Statements | H227-H315-H319-H335 Combustible liquid.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. |
| Precautionary Statements | P210e-P261-P280a-P305+P351+P338-P405-P501a Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. |
