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1H-苯并三唑-1-基氧代三(二甲氨基)磷鎓 六氟磷酸盐
1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate
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产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
3028649 | 1g | 498 | |||
3028649 | 5g | 1097 | |||
3028649 | 25g | 4310 |
产品别名
56602-33-6
1H-苯并三唑-1-基氧代三(二甲氨基)磷鎓 六氟磷酸盐
1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate
BOP Reagent
Castro's Reagent
基本信息
应用 | 1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent. |
备注 | Moisture and light sensitive. Incompatible with strong oxidizing agents. Store in a cool place. Keep the container tightly closed. |
MDL | MFCD00011948 |
EINECS | 260-279-1 |
分子式 | C12H22F6N6OP2 |
分子量 | 442.29 |
熔点 | ca 138° dec. |
灵敏度 | Keep Cold. Moisture Sensitive. Light Sensitive. Store under Nitrogen. |
形态 | Crystalline powder |
溶解性 | Soluble in methanol, acetone and dichloromethane. Insoluble in water. |
Beilstein | 4287025 |
包装组 | II |
危险类别 | 11-36/37/38-44 Highly flammable.Irritating to eyes, respiratory system and skin.Risk of explosion if heated under confinement. |
安全信息
危险等级 | 4.1 |
安全等级 | 26-37-60 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste |
欧盟危险品标志 | |
TSCA | 否 |
GHS危害和防范说明
GHS符号 | |
Hazard Statements | H228-H315-H319-H335 Flammable solid.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. |
Precautionary Statements | P210-P261-P280-P305+P351+P338-P405-P501a Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. |