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[1,2-Bis(diphenylphosphino)ethane]dibromonickel(II)

产品编号:4142769
规格:≥95%
CAS NO:14647-21-3
包装规格:500 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品价格
产品编号包装单位单价(元)国内现货国外库存询价单
4142769500 MG2090
产品别名

14647-21-3

[1,2-Bis(diphenylphosphino)ethane]dibromonickel(II)

dppeNiBr2

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C26H24Br2NiP2
Molecular weight
616.92
Application【应用】
[1,2-Bis(diphenylphosphino)ethane]dibromonickel(II) is a catalyst for a variety of transformations, including:
  • kumada catalyst-transfer polycondensation
  • oxidation of carboranyl phosphine ligands
  • synthesis of nickel-iron dithiolato hydrides
  • hydroformylation of alcohols
  • Ullmann reactions - homocoupling reactions
  • intramolecular aerobic oxidative amination of alkenes
Other Notes【其他说明】
Synthesis of Highly Substituted Isoquinolone Derivatives by Nickel-Catalyzed Annulation of 2-Halobenzamides with Alkynes
产品性质
Assay【测定】
≥95%
form【形式】
powder
mp
322-326 ℃
InChI
1S/C26H24P2.2BrH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChI key
AEGMSHMBRVOLMV-UHFFFAOYSA-L
安全信息
Pictograms【象形图】
GHS08,GHS09
Signal word【警示用语:】
Danger
Hazard Statements
H317 - H334 - H341 - H350i - H360D - H372 - H410
Precautionary Statements
P201 - P273 - P280 - P302 + P352 - P308 + P313
Hazard Classifications【危险分类】
Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1
Storage Class Code【储存分类代码】
6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
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