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Poly-TPD

产品编号:4063474
规格:Mw ≥20,000 g/mol
CAS NO:472960-35-3
包装规格:1 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
40634741 G4000
产品别名

472960-35-3

Poly-TPD

4-Butyl-N,N-diphenylaniline homopolymer

Poly[N,N′-bis(4-butylphenyl) -N,N′-bis(phenyl)-benzidine]

Poly(4-butyl-N,N-diphenylaniline)

Poly(4-butyltriphenylamine)

结构式
基本信息
Linear Formula【线性分子式】
(C22H21N)n
Application【应用】
In a recent study of a double-junction Quantum-Dot Light-Emitting Diodes (QD-LEDs), an impressive high quantum efficiency of 42.2% and a high current efficiency of 183.3 cd/A were achieved, which are comparable to those of the best vacuum-deposited tandem organic LEDs. Such high-efficiency devices are achieved by interface engineering of fully optimized single light-emitting units, which improves carriers′ transport/injection balance and suppresses exciton quenching induced by ZnO, and design of an effective interconnecting layer consisting of Poly-TPD mixed poly(9-vinylcarbazole) (PVK)/poly(3,4-ethylenedioxythiophene):polystyrene sulfonate/polyethylenimine ethoxylated-modified ZnO.

Indoor photovoltaics is one of the best sustainable and reliable energy source for low power consumption electronics such as the rapidly growing Internet of Things.
In another recent study, Perovskite photovoltaic (PPV) cells with a mesoporous PPV (mPPV) structure using typical Spiro-OMeTAD as the hole transport layer (HTL) shows the highest maximum power density (Pmax) of 19.9 μW/cm2 under 200 lux and 115.6 μWcm-2 under 1000 lux (without masking), which is among the best of the indoor PV. When PEDOT:PSS is replaced by Poly-TPD as HTL in the inverted PPV (iPPV) cell, the Pmax under indoor light improves significantly and is comparable to that of the best mesoporous mPPV cell.


Device performance:
iPPV-Poly-TPD
1. under one sun [Pin=100 mW/cm2]
Jsc=21.8 mA/cm2
Voc=1.07 V
FF=73.7%
PCE=17.2%

2. under 1000 lux [200 lux]
Jsc=172.3 mA/cm2
Voc=0.851 V
FF=75.9%
Pmax=111.3 mW/cm
Poly-TPD is a solution processable polymer hole transport material. It′s applications include:
  • Organic Light Emitting Diode (OLED): Hole transport layer / Electron blocking layer (HTL/EBL) Materials
  • Solution-Processed OLED : Polymer hole transport layer
  • Dye-Sensitized Solar Cell (DSSC):Hole transport materials
  • Perovskite Solar Cells:Hole transport material
  • Flexible Printed Electronics:Hole transport layer / Hole injection layer(HTL/HIL) Polymers
产品性质
description【描述】
Solution processable
form【形式】
powder
mol wt【分子量】
Mw ≥20,000 g/mol
Orbital energy【轨道能量】
HOMO -5.2 eV 
LUMO -2.4 eV 
storage temp.【储存温度】
15-25℃
安全信息
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
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