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(S)-SDP

产品编号:3337385
规格:≥95%
CAS NO:528521-86-0
包装规格:50 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
333738550 MG2170
产品别名

528521-86-0

(S)-SDP

(S)-(-)-7,7′-Bis(diphenylphosphino)-2,2′,3,3′-tetrahydro-1,1′-spirobiindene

(S)-7,7′-Bis(diphenylphosphino)-1,1′-spirobiindane

(S)-(-)-7,7′-双(二苯基膦基)-2,2′,3,3′-四氢-1,1-螺双茚

(S)-7,7'-双(二苯基磷酰)-1,1'-螺二氢茚

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C41H34P2
Molecular weight
588.66
MDL number
MFCD08459344
PubChem Substance ID【PubChem化学物质编号】
329762227
NACRES
NA.22
General description【一般描述】
(S)-SDP is a chiral diphosphine reagent used in the asymmetric hydrogenation of ketones catalyzed by transition metal. It is also used in hydrosilylation or cyclization of 1,6-enynes.
Application【应用】
(S)-SDP can be used:
  • As a ligand in the ruthenium-catalyzed asymmetric hydrogenation of cyclic ketones to give cycloalkanols.
  • To prepare ruthenium complexes, which are used in the asymmetric hydrogenation of different prochiral ketones.

产品性质
Assay【测定】
≥95%
optical activity【旋光性】
[α]22/D −191°, c = 1 in chloroform
mp
199-204 ℃
storage temp.【储存温度】
−20℃
SMILES string
C1CC2(CCc3cccc(P(c4ccccc4)c5ccccc5)c23)c6c1cccc6P(c7ccccc7)c8ccccc8
InChI
1S/C41H34P2/c1-5-17-33(18-6-1)42(34-19-7-2-8-20-34)37-25-13-15-31-27-29-41(39(31)37)30-28-32-16-14-26-38(40(32)41)43(35-21-9-3-10-22-35)36-23-11-4-12-24-36/h1-26H,27-30H2
InChI key
DKZNVWNOOLQCMJ-UHFFFAOYSA-N
packaging【包装】
50 mg in amber glass bottle
安全信息
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
Eyeshields, Gloves, type N95 (US)
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