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(S)-(-)-(6,6′-二甲氧联苯-2,2′-二基)双(二苯基膦)
(S)-(-)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
产品编号: | 3331486 |
规格: | ≥97%, optical purity ee: ≥99% |
CAS NO: | 133545-17-2 |
包装规格: | 50 G,100 G |
产品类别: | 进口试剂 |
品牌: | Sigma-Aldrich |
优惠价: | 立即咨询 |
产品价格查看更多规格...
产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
3331486 | 50 G | 126660 | |||
3331486 | 100 G | 171700 |
产品别名
133545-17-2
(S)-(-)-(6,6′-二甲氧联苯-2,2′-二基)双(二苯基膦)
(S)-(-)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
(S)-(-)-MeO-BIPHEP
SL-A101-2
(S)-(-)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl
(S)-(-)-2,2′-双(二苯基膦)-6,6′-二甲氧-1,1′-联苯
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C38H32O2P2 |
Molecular weight | 582.61 |
Beilstein | 4790083 |
MDL number | MFCD03095430 |
PubChem Substance ID【PubChem化学物质编号】 | 24857759 |
NACRES | NA.22 |
General description【一般描述】 | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. |
Application【应用】 | Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas. Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination Atropisomeric MeOBIPHEP ligands
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产品性质
Quality Level【质量水平】 | 100 |
Assay【测定】 | ≥97% |
optical purity【光学纯度】 | ee: ≥99% |
greener alternative product characteristics【环保替代产品特性】 | Catalysis Learn more about the Principles of Green Chemistry. |
greener alternative category【环保替代产品分类】 | Aligned |
SMILES string | COc1cccc(P(c2ccccc2)c3ccccc3)c1-c4c(OC)cccc4P(c5ccccc5)c6ccccc6 |
InChI | 1S/C38H32O2P2/c1-39-33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)38-34(40-2)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3 |
InChI key | KRJVQCZJJSUHHO-UHFFFAOYSA-N |
packaging【包装】 | 1, 5 g in glass bottle 500 mg in glass bottle Bottomless glass bottle. Contents are inside inserted fused cone. |
安全信息
Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
WGK | WGK 3 |
Personal Protective Equipment【个人防护装备】 | Eyeshields, Gloves, type N95 (US) |