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4-乙酰苯基硼酸

4-Acetylphenylboronic acid
产品编号:3309318
规格:95%
CAS NO:149104-90-5
包装规格:5 G,25 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
33093185 G356
330931825 G1550
产品别名

149104-90-5

4-乙酰苯基硼酸

4-Acetylphenylboronic acid

结构式
基本信息
Linear Formula【线性分子式】
CH3COC6H4B(OH)2
Molecular weight
163.97
MDL number
MFCD01074667
PubChem Substance ID【PubChem化学物质编号】
24870686
NACRES
NA.22
General description【一般描述】
4-Acetylphenylboronic acid is a boronate, belongs to a class of synthetic organic compounds. It reacts rapidly with peroxynitrite (ONOO(-)) to form stable hydroxy derivatives. It undergoes Suzuki coupling with 4-bromotriphenylamine catalyzed by dichlorobis(triphenylphosphine)Pd(II), during the synthesis of dendrimers.
Application【应用】
Reactant involved in:
  • Palladium-catalyzed decarboxylative coupling
  • Copper-catalyzed hydroxylation
  • Palladium-catalyzed Suzuki-Miyaura cross-coupling
  • Cross-coupling with α-bromocarbonyl compounds
  • Oxidation catalyzed by Baeyer-Villiger monooxygenases
  • 1,5-substitution reactions

4-Acetylphenylboronic acid was used in the synthesis of 4′-azidoacetophenone.
Other Notes【其他说明】
含有不定量的酸酐
产品性质
Quality Level【质量水平】
100
Assay【测定】
95%
mp
240-244 ℃ (lit.)
SMILES string
CC(=O)c1ccc(cc1)B(O)O
InChI
1S/C8H9BO3/c1-6(10)7-2-4-8(5-3-7)9(11)12/h2-5,11-12H,1H3
InChI key
OBQRODBYVNIZJU-UHFFFAOYSA-N
packaging【包装】
5, 25 g in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319 - H335
Precautionary Statements
P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
dust mask type N95 (US), Eyeshields, Gloves
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