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三辛基氧化膦

Trioctylphosphine oxide
产品编号:3255556
规格:for extraction analysis, ≥98.5%
CAS NO:78-50-2
包装规格:10G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
325555610G610
产品别名

78-50-2

三辛基氧化膦

Trioctylphosphine oxide

TOPO

(Oct)3PO

结构式
基本信息
Linear Formula【线性分子式】
[CH3(CH2)7]3PO
Molecular weight
386.63
Beilstein
1796648
EC number【EC 号】
201-121-3
MDL number
MFCD00002083
PubChem Substance ID【PubChem化学物质编号】
329747118
NACRES
NA.22
Application【应用】
Catalyst in:
  • Preparation of tetradentate planar-chiral hydroxy-substituted ferrocenecarboxaldimine Schiff base ligands
  • Reactions of allyl esters with hydrosilanes
  • Asymmetric cyanosilylation of aldehydes
  • Preparation of chlorothiol formates from thiols and phosgene
Legal Information【法律信息】
TOPO is a registered trademark of Life Technologies
产品性质
Quality Level【质量水平】
200
grade【等级】
for extraction analysis
Assay【测定】
≥98.5% (GC)
≥98.5%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
impurities【杂质】
≤0.2% free acid (as H3PO4)
≤0.5% water
bp
201-202 ℃/2 mmHg (lit.)
mp
50-52 ℃ (lit.)
52-55 ℃
cation traces【痕量阳离子】
Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤10 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤10 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg
functional group【官能团】
phosphine
SMILES string
CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC
InChI
1S/C24H51OP/c1-4-7-10-13-16-19-22-26(25,23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3
InChI key
ZMBHCYHQLYEYDV-UHFFFAOYSA-N
安全信息
Pictograms【象形图】
GHS05
Signal word【警示用语:】
Danger
Hazard Statements
H315 - H318
Precautionary Statements
P280 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Dam. 1 - Skin Irrit. 2
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(F)【闪点(F)】
230.0 °F - closed cup
Flash Point(C)【闪点(C)】
110 ℃ - closed cup
Personal Protective Equipment【个人防护装备】
dust mask type N95 (US), Eyeshields, Gloves
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