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硅胶负载 TEMPO
TEMPO on silica gel
产品别名
硅胶负载 TEMPO
TEMPO on silica gel
2,2,6,6-Tetramethyl-1-piperinyloxy, free radical on silica gel
SiliaCAT TEMPO
硅胶负载 2,2,6,6-四甲基-1-哌啶基氧自由基
结构式
基本信息
MDL number | MFCD04975412 |
NACRES | NA.22 |
General description【一般描述】 | FeCl3.6H2O/TEMPO (2,2,6,6-tetramethylpiperidine 1-oxyl radical) in the presence of silica gel has been employed as catalyst for oxidation of alcohols to the corresponding aldehydes and ketones. Doping of stable organic nitroxyl radical TEMPO, over different silica matrices affords reusable highly selective catalysts for various alcohol oxidation reactions. TEMPO-supported on silica gel catalyzed-Anelli oxidation of alcohols has been reported. |
Application【应用】 | 用于醇的 Anelli 氧化反应的可回收催化剂。 |
Legal Information【法律信息】 | SiliaCat is a registered trademark of Silicycle, Inc. |
产品性质
Quality Level【质量水平】 | 100 |
storage temp.【储存温度】 | 2-8℃ |
packaging【包装】 | 5, 25 g in glass bottle |
安全信息
Pictograms【象形图】 | GHS07 |
Signal word【警示用语:】 | Warning |
Hazard Statements | H302 - H315 - H319 |
Precautionary Statements | P264 - P270 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 |
Hazard Classifications【危险分类】 | Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 |
Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
WGK | WGK 3 |